Analyze porosity and porosimetry in the laboratory

Characterization of materials Problem solving R&D support
More than 140 people
More than 140 people at your service
5200 m² laboratory
5200 m² laboratory + 99% of services are provided in-house
+2200 clients
+2200 clients en France et à l'étranger

Your need: identify the internal and surface structure of your materials

Our porosity analysis laboratory offers porosimetry services, combined with other complementary techniques to provide you with precise and usable data.

Objectives of porosity analysis

assess the actual porosity of a material
optimize performance (mechanical, fluidic, thermal)
control quality and ensure compliance with specifications

Our solutions: carry out a porosity analysis to characterize and optimize your materials

Call on FILAB, porosimetry laboratory

For over 30 years, our laboratory has had the expertise and analytical resources necessary to meet specific porosity analysis needs.

We support industries in the precise characterization of the internal and surface structure of their materials, offering reliable, customized analyses tailored to each problem.

Our porosity analysis in detail

Porosity analysis transforms an often invisible property into a controllable parameter, thereby securing, improving, and innovating industrial processes.

  • Quality control/compliance: detecting internal defects, density variations, or unexpected porous areas that could compromise performance or cause failures.
  • Process optimization: adjusting sintering, compacting, firing, or coating parameters based on the measured porosity level.
  • Formulation/material comparison: comparing the performance of alternative materials or batches in terms of porosity (and therefore fluid transport, permeability, capillarity, etc.).
  • Predicting functional behavior: calculating permeability, thermal conductivity, mechanical strength, fluid diffusion (liquid/gas), etc., based on porosity measurements.
  • Predict functional behavior: calculate permeability, thermal conductivity, mechanical strength, fluid diffusion (liquid/gas), etc., based on porosity measurements.
  • Failure problems: identify porous areas responsible for cracking, internal corrosion, infiltration, or loss of integrity.

Our technical means for measuring porosity

At the FILAB laboratory, the main means of characterizing porosity are:

Mercury porosimetry

(Hg porosimetry)

BET method

(gas adsorption, typically N₂ model BJH°)

Techniques adapted to each need

The choice of technique for your porosity analysis depends on several criteria, which we evaluate with you:

Pore size range to be measured

  • If you have very small pores (micropores < 2 nm, mesopores up to ~50 nm)
  • If your pores are larger, in the nanometer to micrometer range or even larger
  • For very small pores and/or closed porosity

Type of porosity (open vs. closed)

  • Mercury porosimetry only penetrates open pores.
  • The BET technique measures adsorption on pores accessible to the gas molecule.

Objectives of porosity measurements

  • To obtain a pore diameter distribution (size, volume)
  • To determine the true density/total porosity
  • To perform rapid quality control
  • To model fluid behavior

Often, for complete characterization, we recommend a combined approach: for example, BET, Hg porosimetry, and pycnometer, depending on the ranges of interest.

Materials concerned and industries

Our porosity analysis services are designed for a wide range of industrial materials:

  • Metallic materials: metal alloys
  • Powders: metal powders, PAH powders, etc.
  • Ceramics and glass
  • Polymers and composites

Which techniques should be used to measure porosity?

Learn more

Mercury porosimetry is a technique that can analyze a wide range of pore diameters, from a few nanometers to several hundred micrometers. It offers excellent resolution for open porosity and allows for fine characterization of the pore structure. However, it is limited to mercury-compatible materials, cannot accurately detect closed pores, and requires special precautions due to mercury toxicity.

The BET technique (BJH model nitrogen adsorption) relies on the adsorption of gas molecules such as nitrogen or argon to measure the specific surface area and the distribution of microporosity and mesoporosity. It is distinguished by its very good resolution in these pore ranges and by its non-destructive nature, as it does not require forced intrusion.

FAQ

What is the difference between open porosity and closed porosity?

Open porosity is that which communicates with the exterior of the material, and is therefore accessible to fluids or gases. Closed porosity is isolated within the material, not connected externally. Methods such as Hg porosimetry only measure open porosity.

What is the minimum and maximum pore size that can be analyzed?

This depends on the equipment. Typically, Hg porosimetry covers diameters from a few nanometers (or even ~3 nm) to several hundred micrometers, or even millimeters depending on the instrumentation.

Can we combine several techniques for the same assessment?

Yes, it is often recommended to cover the entire pore size range (micropores via BET, macropores via Hg porosimetry) and cross-reference the results. The synergy of the techniques gives a more complete view.

The filab advantages
A highly qualified team
A highly qualified team
Responsiveness in responding to and processing requests
Responsiveness in responding to and processing requests
A COFRAC ISO 17025 accredited laboratory
A COFRAC ISO 17025 accredited laboratory
(Staves available on www.cofrac.com - Accreditation number: 1-1793)
A complete analytical park of 5,200m²
A complete analytical park of 5,200m²
Tailor-made support
Tailor-made support
Video debriefing available with the expert
Video debriefing available with the expert
Thomas GAUTIER Head of Materials Department
Ask for your quote